Name | Quinolinium Dichromate |
Synonyms | quinolin-1-ium QUINOLINIUM DICHROMATE Quinolinium Dichromate |
CAS | 56549-24-7 |
Molecular Formula | C18H16Cr2N2O7 |
Molar Mass | 476.32 |
Melting Point | 164-167°C (dec.)(lit.) |
Appearance | Powder |
Color | Dark yellow to orange |
Storage Condition | Refrigerator |
MDL | MFCD00059108 |
Risk Codes | R45 - May cause cancer R8 - Contact with combustible material may cause fire R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed. R36/37/38 - Irritating to eyes, respiratory system and skin. |
Safety Description | S53 - Avoid exposure - obtain special instructions before use. S17 - Keep away from combustible material. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S27 - Take off immediately all contaminated clothing. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) |
UN IDs | 1479 |
Hazard Class | 5.1 |
Packing Group | III |
application | quinoline dichromate (QnDC) is an oxidant. The most commonly used Cr(VI) reagent is to oxidize primary and secondary alcohols to the corresponding carbonyl compounds, which can be used in laboratory research and development and chemical and pharmaceutical synthesis. |
Preparation | Synthesis of quinoline dichromate: Quinaridine (28cm 3,0.2mol) is slowly added to a cooling solution of 20g CrO3(0.2mol) in 20 cm3 H2O. After 0.5 hours, the reaction mixture was diluted with 40cm3 of acetone and cooled to -15°C. Yellow crystals were collected and washed with acetone. It was recrystallized from H2O and dried in vacuum for about 2 h. 88% yield. Melting point 150-151 ℃. |